TXM

Understanding the Reactivity of CoCrMo-implant Wear Particles

March 30, 2018

CoCrMo-based metal-on-metal hip implants were introduced, particularly for younger patients, due to their superior wear resistance and theoretical mechanical advantages over other hip implant materials (especially the most commonly used metal-on-polyethylene).  However, these CoCrMo-based implants suffered an unexpectedly high failure rate1 raising concerns over their safety, and leading to considerable attention in the literature on explaining the reasons behind their failure.

Understanding how Li-rich Cathode Materials Degrade Using X-ray Diffraction, Spectroscopy, and 3D Nano Imaging

September 30, 2016

The continuing development of better lithium-ion batteries, which are common in consumer electronics, depends on improvements in the batteries’ chemical materials. Over the charge/discharge cycle of the battery, the electrochemistry and morphology of the material change, which can cause steric stresses and defects, leading to decreased battery performance. Modifications of the lithium compounds used at the cathode can help the batteries hold more charge and keep charge better over many charge/discharge cycles.

Persistent State-of-Charge Heterogeneity in Fully Relaxed Battery Electrode Particles

July 29, 2016

Most portable electronic devices depend on lithium ion batteries for energy storage. The current capabilities of lithium ion batteries are insufficient for the requirements of emerging and growing industries, like electric cars and renewable energy storage. These industries require batteries that are longer-lived, smaller, lighter, and cheaper. One way to improve lithium ion batteries is to increase the charging cutoff voltage, which increases the energy that can be stored in the battery, but it leads to shortened battery life, called capacity fade. A team of scientists has discovered a new mechanism for capacity fade.

Nucleation and Growth of Electrodeposited ZnO Visualized by in-Situ X-ray Microscopy

June 30, 2016

Zinc oxide (ZnO) is used to coat optoelectronic technology, which includes components that create and/or detect light, x-rays, infrared, or other forms of radiation. When ZnO properly crystallizes, it creates a transparent conducting film. The performance of the film is compromised when there is disruption in nucleation and growth of ZnO. A team of scientists collaborated to study the process of electrodeposition of ZnO into films.

Mapping Metals Incorporation of a Single Catalyst Particle Using Element Specific X-ray Nanotomography

March 31, 2015

One of the most important processes used in petroleum refineries is called fluid catalytic cracking (FCC). This chemical process converts large or heavy molecules of crude oil into smaller and lighter hydrocarbons, such as gasoline. This useful conversion is due in great part to a tiny catalyst particle just 50 to 150 millionths of a meter in diameter. The particle consists of a complex mixture of silica-alumina, clay and zeolite in a porous structure that enables the crude oil molecules to flood the material and reach the catalytically active areas within the particle. After the conversion process, this structure also allows the lighter molecules to leave the catalyst.

Non-Equilibrium Pathways during Electrochemical Phase Transformations in Single Crystals Revealed by Dynamic Chemical Imaging at Nanoscale Resolution

February 27, 2015

Lithium-ion batteries, the mobile power source for most electronic devices, play an important role in everyday life. In the coming decades, they could play an even greater role, powering electric vehicles or storing electrical energy for the grid – if researchers can find ways to improve them.

In particular, the energy density of current batteries is limited by the capacity of the positive electrode, which in turn is determined by the properties and concentration of its active material. By better understanding this material and its limitations, researchers hope to design the highest capacity electrodes possible.

In situ Nanotomography and Operando Transmission X-ray Microscopy of Micron-sized Ge Particles in Battery Anodes

August 29, 2014

Rechargeable lithium-ion batteries are widely used in a variety of applications, ranging from consumer electronics to electric vehicles. Their breadth of use makes the development of new, high-capacity battery materials highly desirable. Yet, the progress of lithium-ion technology has been rather slow over the past decades. One promising approach to enhancing the capacity of lithium-ion batteries is to use silicon or germanium anodes that form alloys with lithium during cycling. Unfortunately, these electrodes fail after a few charge cycles for reasons that had not been fully understood. A recent study has now revealed that fracturing of the anode material during battery operation causes the anodes to malfunction.

Nanoscale Morphological and Chemical Changes of High Voltage Lithium-Manganese Rich NMC Composite Cathodes with Cycling

August 29, 2014

Responsible, eco-friendly and sustainable use of energy is one of the biggest challenges in today’s world. Current rates of energy consumption demand the development of efficient ways to store energy, for instance in safe and durable rechargeable batteries. However, repeated charge cycles degrade batteries over time, eventually leading to their failure. Researchers from the University of Science and Technology of China, SSRL and Oak Ridge National Laboratory have recently developed a new approach to visualize and quantify changes in battery materials during electrochemical cycling – providing crucial information for a better understanding of battery failure and potential improvements of energy storage materials.  

A Five-dimensional Visualization of the Pressure-induced Phase Transition in BiNiO3

February 28, 2014

It is common knowledge that materials expand when heated. However, a chemical compound known as BiNiO3 proves to be quite extraordinary in that it contracts with rising temperature. By mixing BiNiO3 with “conventionally” expanding materials, it becomes possible to produce composite materials with zero or other desired thermal expansion values – a possibility with great potential for engineering and other applications. The same transition from a low-density to a high-density phase of BiNiO3 observed for increasing temperatures can also be induced by applying high pressure.

Percolation Explains How Earth’s Iron Core Formed

November 27, 2013

Earth’s inner structure is organized into layers. The outermost crust overlays the mantle, which, in turn, surrounds our planet’s core. The crust and mantle are mainly composed of silicate rocks. In contrast, Earth’s core is metallic, containing predominantly iron. But how did iron separate from the silicates in order to form the metallic core during Earth’s evolution? Researchers have recently provided evidence that the percolation of liquid iron alloys through a solid silicate matrix can explain the formation of Earth’s core.

Mesoscale Phase Distribution in Li-ion Battery Electrode Materials

May 31, 2013

Li-ion batteries are key devices in the effort to develop efficient chemical energy storage from sustainable energy sources. However, any effort to optimize battery performance requires a deeper understanding of the fundamental mechanisms of diffusion and phase transformation in battery electrodes.

Nanoscale Examination of Microdamage in Sheep Cortical Bone

April 30, 2013

A study, recently published in PLoS ONE by researchers from Cornell University, Hospital for Special Surgery, and SSRL, describes nanoscale visualization of micro-damage in cortical bone tissue using x-ray negative staining and synchrotron-based x-ray imaging. The first study to examine bone damage at the nanoscale using full-field x-ray imaging in cortical bone, it provides new insights into bone damage and propagation of fractures.

Imaging and Speciation of CeO2 and ZnO Nanoparticles in Soybean (Glycine max): Nanoparticle Transfer to the Food Chain

February 28, 2013

The global production of engineered nanoparticles (ENPs) is currently a trillion-dollar industry. However, ENPs behave differently than their bulk counterparts, mostly due to increased specific surface area and reactivity, which has raised concerns about their fate, transport, and toxicity in the environment. A growing number of products containing ENPs are already on the market, including ZnO nanoparticles widely used sunscreen, gas sensors, pigments and other applications, and nanoceria (Ce ENPs) used as catalysts for internal combustion and oil cracking processes.

Fischer-Tropsch Catalyst Nanoscale Chemistry under Realistic Working Conditions

November 30, 2012

Olefins are the basic building blocks for many products from the petrochemical industry and are currently produced by steam cracking of naphtha or ethane, but increasing oil and gas prices are driving the industry toward producing olefins from syngas derived from cheaper feedstocks via the Fischer-Tropsch process instead. A team of scientists used full-field Transmission hard X-ray Microscopy (TXM) and a special reactor designed and built at SSRL and installed on SSRL Beam Line 6-2 to learn more about the catalyst at the heart of the Fischer-Tropsch-to-Olefins (FTO) process.

SSRL Discoveries Point to Better Batteries

October 31, 2012

Researchers at SSRL, General Motors, Imperial College London, National Taiwan University, and elsewhere have recently begun experimenting with 3-D transmission X-ray microscopy (TXM), in order to gain new insight into the microstructure of battery electrodes.

X-ray Characterization of Lithium-Sulfur Batteries in Action

June 22, 2012

Dramatic improvements in energy storage devices are essential to meet the increasing need to move away from fossil fuels and toward clean, renewable energy. Rechargeable lithium-sulfur (Li-S) batteries hold great potential for high-performance energy storage systems because they have a high theoretical specific energy, low cost, and are eco-friendly; but a better understanding of how the battery functions is required to design improvements for higher efficiency and capacity.

3D View Inside the Skeleton with X-ray Microscopy: Imaging Bone at the Nanoscale

June 28, 2010

The 3D structure of bone is critical for maintaining strength. Skeletal diseases such as osteoporosis and environmental conditions such as weightlessness, radiation, and vitamin D deficiency can affect bone structure. Understanding the 3D structure of bone is critical to understanding how these conditions affect bone's form and function.

Defining the processes controlling arsenic uptake by rice (Oryza sativa L.)

November 29, 2010

Rice, the grain that provides more than one-fifth of the world population's calories, can become a health hazard if contaminated with arsenic. Such contamination, a surprisingly widespread occurrence, takes place in areas where soil or irrigation water is tainted by naturally occurring arsenic--including broad swaths of south and southeastern Asia. Studies have suggested that the natural iron coating around the roots of rice plants may serve as an important barrier to arsenic uptake because arsenic in its oxidized form has an affinity for iron. A team of Stanford and SSRL researchers recently sought to learn just how significant a barrier iron provides.

Better Batteries through Nanoscale 3D Chemical Imaging

July 25, 2011

As an important step toward reducing oil dependence and greenhouse gas production, electric vehicles are becoming more and more prevalent. However, one major barrier remains: their batteries. Today’s lithium-ion technology has yet to meet energy density, cost, life cycle and safety goals.

X-ray Nanotomography Imaging for Circuit Integrity

September 26, 2011

As cell phones, computers, and other electronic equipment have become part of our daily lives, so too have integrated circuits.  Also known as microchips, these semiconductors patterned with trace elements serve as the brains of electronic devices, controlling processes, storing data, and converting information from digital to analog, to name only a few applications.  With their increasing prevalence, however, comes the increasing prevalence of malicious attacks.  Integrated circuits are susceptible to "hardware Trojans" that can be inserted during production, testing, or distribution to cause failure or compromise the circuit.

"Seeing" Mercury Methylation in Progress

December 18, 2009

High levels of mercury in our diets can have adverse effects on our health, and fish are a major source of dietary mercury. Because of a process called biomagnification, mercury levels in fish can build up to be at a much higher concentration than in the surrounding water. The mercury that accumulates in the tissue of fish is in the form of methylmercury, but this is not necessarily the chemical form that pollutes the water. Microorganisms living in the rhizosphere, or root zone, of plants are responsible for much of the methylation of mercury.

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