X-ray scattering

Shedding New Light on the Study on High-Tc Cuprates

June 13, 2022

In the ongoing quest for a room-temperature superconductor, scientists are examining the normal, or ground, state of the highest temperature superconductors currently known. It is thought that understanding the particularities of the normal state in these materials, for example the mysterious pseudogap phase, would give clues to how to engineer materials that can lead to superconducting behavior at even higher temperatures. When studying the normal state, especially its ground state, the superconducting state needs to be quenched; otherwise it will interfere. Two established methods for quenching the superconducting state are applying an external magnetic field and using an optical pump, but the relationship between the states achieved by these two methods is unclear.

Powerful X-rays Explore the Molecular Composition in a Historical Collection of Australian Plant Resins

June 13, 2022

A collection of native Australian plant resins sampled over one hundred years ago serves as a time capsule for scientists to study using modern techniques. The well-annotated and well-preserved samples by unknown collectors feature four species important to Aboriginal Australian technology and culture going back tens of thousands of years. A team of scientists employed advanced x-ray spectroscopy to decipher the molecular composition of this unique collection of samples.

Understanding Reaction Pathways Leading to MnO2 Polymorph Formation

July 31, 2018

Metastable materials are materials that exist in their higher-energy configurations. They will eventually transform into their lowest energy form, given a certain amount of time. The classic example is diamond, which given enough time will change into graphite. They can have desired functionalities that make them useful in a variety of applications, such as in electronics, batteries, and catalysts. However, making metastable materials is not an easy job.

Negative-pressure Polymorphs Made by Heterostructural Alloying

April 30, 2018

Polymorphism is a fascinating natural phenomenon across many areas of materials science – from small molecules in chemistry, to minerals in geology, to drugs in pharmaceutical industry, to solid-state materials in electronics. High-density polymorphs with unique properties, such as a transparent insulating form of sodium (1) are routinely synthesized under compressive strain at very high pressure. In contrast, applying large negative pressure is very difficult, because large tensile strain usually causes materials to rupture.

Watching Ions Hop in Superionic Nanomaterials

March 31, 2013

For the first time, ultrafast x-ray scattering and spectroscopic measurements carried out at SSRL, the Advanced Light Source (ALS) and the Advanced Photon Source (APS) captured the atomic-level dynamics of a superionic nanocrystal as it transformed.

Structural Polymorphism of the Actin-Espin System: A Prototypical System of Filaments and Linkers in Sterocilia

July 30, 2007

Scientists exploring the physics of hearing have found an underlying molecular cause for one form of deafness. The team, led by Gerard Wong, Professor of Materials Science and Engineering, of Physics, and of Bioengineering at the University of Illinois at Urbana-Champaign, report their findings in the February 2007 issue of the journal Physical Review Letters.

Cationic Liposome-Microtuble Complexes: Lipid-Protein Bio-Nanotubes with Open or Closed Ends

October 31, 2005

Microtubules, 25 nanometer scale hollow tubules, are critical components in a broad range of functions in eukaryotic cells -- from providing tracks for the transport of cargo to forming the spindle structure for chromosome segregation before cell division. They are used as nanometer scale tracks in neurons for the transport of neurotransmitter precursors and enzymes to synaptic junctions in nerve cell communication.

Remembrance of Things Past

July 29, 2004

New evidence is overturning the assumption that the thermal oxide grown on single crystal silicon is completely amorphous. SSRL researchers Anneli Munkholm (now at Lumileds Lighting) and Sean Brennan recently published work in Physical Review Letters showing that there is residual order within the oxide. The thermal oxide film on silicon has been studied extensively for decades because these oxides form the basis of most of the integrated circuits used in modern electronics. The new results have implications for theoretical models of the oxidation process.

The Role of Surface X-ray Scattering in Electrocatalysis

January 31, 2003

Electrocatalysis is the science of modifying the overall rates of electrochemical reactions so that selectivity, yield and efficiency are maximized. Studies in electrocatalysis have resulted in tools such as highly selective multicomponent gas mixture sensors and better electrocatalysts for the fuel cells. Markovic and Lucas have been very active in studying the mechanisms by which these catalysts operate and developing in-situ surface x-ray scattering (SXS) techniques for their studies. 

Effects of Thermal Annealing On the Morphology of Polymer–Fullerene Blends for Organic Solar Cells

January 31, 2011

Organic solar cells, which use organic polymers or small organic molecules to convert sunlight into a useable form of energy, are a promising new tool for providing inexpensive, environmentally friendly energy. To date organic solar cells have demonstrated comparatively low rates of efficiency, stability and strength.  However, there is much room for improvement before the theoretical efficiency limits are reached.

Fragile Magnetic Ground State in Half-Doped Manganite: Orbital Instability

August 29, 2011

New, designer materials—the ones that can carry a charge without depleting it or offer dramatically faster, more efficient computer memory—take advantage of the interplay between the materials’  degrees of freedom (in other words, the parameters that contribute to the materials’ state).  One such promising material, made of the elements lanthanum, strontium, and manganese, has previously demonstrated unusual magnetic properties depending on the particular mixture of lanthanum and strontium.

Enhanced Charge Transport in Printed Small Organic Semiconductor Thin Films due to Strained Molecular Packing

January 30, 2012

Organic semiconductors could usher in an era of foldable smart phones, better high-definition television screens and clothing made of materials that can harvest energy from the sun needed to charge your iPod or iPad, but there is one serious drawback: Organic semiconductors, while inexpensive, do not conduct electricity very well.

Towards the Chemically Specific Structure of Amorphous Materials: Anomalous X-ray Scattering from a Molybdenum-Germanium Alloy

November 29, 2002

Attempting to determine and describe the atomic arrangements in an amorphous material is a daunting prospect. A considerable advance has been made in the anomalous X-ray scattering approach to determining these arrangements in materials containing two atomic species.

Nature of Charge Order in the Layered Manganite La1-xSr1+xMnO4

September 28, 2001

The strong electron correlations in transition metal oxides give rise to such phenomena as high-temperature superconductivity in layered cuprates and to stripe-like order in layered cuprates and nickelates. In the case of the manganites, an additional strong electron-lattice interaction leads to a very rich phase diagram in which structural, magnetic, and transport properties are intimately related. Colossal magnetoresistance (CMR) has been observed in the perovskite and double-layer manganites, but not in the single-layer system La1-xSr1+xMnO4 (Mn214). 

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