Photoemission spectroscopy

A New Look at Biological Electron Transfer: Electronic Relaxation in Rubredoxins

June 30, 2003

Electron transfer, the process of moving an electron from one place to another, is vital to almost all chemical systems. It is a fundamental process in organic synthesis, in catalysis, and in the biochemistry of all living organisms. In biological systems, transition metal centers (such as iron and copper) often play the central role in an electron transfer protein, shuttling electrons within or between proteins.

Experimental Station 13-2

BL13-2 has stations designed for surface and solid state experiments. The SSE station has an electron spectrometer (SES-R3000, VG-Scienta) for photoemission spectroscopy and Auger electron yield X-ray absorption spectroscopy, and a Ni coated elliptical grating spectrometer for C 1s, N 1s and O 1s x-ray emission spectroscopy. A horizontally mounted manipulator is provided for experiments with a minimum sample temperature of about 40 K. The manipulator transfers samples between the preparation chamber and the main chamber.

Experimental Station 10-1

BL10-1 is primarily used for x-ray absorption and photoemission spectroscopies. The optics and control software can be run in continuous scanning mode. A few facility chambers, including cryogenic sample handling and detectors are available upon request.

Experimental Station 8-2

BL8-2 can be used to probe a wide range of core levels using photoemission and X-ray absroption spectroscopy.
See video on the role of aluminum foil in vacuum chamber 'bakeouts.'

Experimental Station 8-1

BL8-1 is equipped with a post-monochromator beam-splitting mirror to allow for two sample chamber locations. BL8-1a accommodates roll-on user chambers. BL8-1b is under modification to provide energy range from 2eV to 10eV. The mirror cooling system was upgraded in FY04 and the BL8-1 stations are SPEAR3 500 mA compatible. Stations 8-1a and 8-1b cannot be used simultaneously. 

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