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Scientific Highlight
UTEP M.R.T.I.
CNRS/IRC

 




29 November 2004

  Structural Studies of Catalytically Stabilized Industrial Hydrotreating Catalysts

summary written by Raven Hanna, SLAC Communication Office

Myriam Perez De la Rosa, Gilles Berhault, Apurva Mehta and Russell R. Chianelli

 
 


As oil prices rise, so will the market for cheaper forms of petroleum-based fuels. Cheaper petroleum contains more impurities, which will aggravate environmental problems, like heavier air pollution and acid rain. Purifying the fuel will alleviate the environmental harm. Sulfur impurities can be removed by treatment with catalytic materials such as Molybdenum disulfide (MoS2).

Researchers from the University of Texas at El Paso, CNRS and SSRL are collaborating to study the morphology of catalytically active forms of MoS2 and how the morphology changes over time under the high pressures of industrial desulfurization reactors. Through x-ray structure analysis, they determined that the catalyst changes morphology after several years in a high-pressure industrial reactor without significant change to its activity. The researchers were surprised by these findings, since they contradict the traditional understanding of how morphology affects activity. This study has enabled a better understanding of the mechanism of MoS2 catalytic action, which could lead to the design of more active and longer lasting catalysts to purify fuels.

To learn more about this research see the full scientific highlight at:
http://www-ssrl.slac.stanford.edu/research/highlights_archive/mos2.html

Perez De la Rosa M., Texier S., Berhault G., Camacho A., Yacaman M.J., Mehta A., Fuentes S., Montoya J.A., Murrieta F., Chianelli R.R.,: J. Catal. 225 (2004) 288.