As oil prices rise, so will the market for cheaper forms of petroleum-based
fuels. Cheaper petroleum contains more impurities, which will aggravate
environmental problems, like heavier air pollution and acid rain. Purifying
the
fuel will alleviate the environmental harm. Sulfur impurities can be removed
by
treatment with catalytic materials such as Molybdenum disulfide
(MoS2).
Researchers from the University of Texas at El Paso, CNRS and SSRL are
collaborating to study the
morphology of catalytically active forms of MoS2 and how the
morphology changes over time under the high pressures of industrial
desulfurization reactors. Through x-ray structure analysis, they determined
that the catalyst changes morphology after several years in a high-pressure
industrial reactor without significant change to its activity. The researchers
were surprised by these findings, since they contradict the traditional
understanding of how morphology affects activity. This study has enabled a
better understanding of the mechanism of MoS2 catalytic action,
which could lead to the design of more active and longer lasting catalysts to
purify fuels.
To learn more about this
research see the full scientific highlight at:
http://www-ssrl.slac.stanford.edu/research/highlights_archive/mos2.html
Perez De la Rosa M., Texier S., Berhault G., Camacho A., Yacaman M.J., Mehta
A., Fuentes S., Montoya J.A., Murrieta F., Chianelli R.R.,: J. Catal.
225 (2004) 288.